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OXIDATION OF CO BY NO2 OVER PD(100)

被引：6
作者：
GRAHAM, GW
LOGAN, AD
SHELEF, M
机构：
[1] Ford Motor Co, Dearborn, MI
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 07期
关键词：
D O I：
10.1021/j100058a003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rate of CO oxidation by NO2 over Pd(100) was measured at CO and NO2 partial pressures of 1 and 0.05 Torr, respectively, and temperatures in the range 385-415 K. These results explain the non-Arrhenius behavior previously reported for the CO2 formation rate in the CO + O-2 + NO reaction over Pd(100) and show that the difference between Pd and Rh is even more dramatic for the CO + NO2 + NO reaction than for the CO + O-2 + NO reaction.
引用
收藏
页码：1746 / 1747
页数：2
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