A NEW PROCEDURE FOR CONSTRUCTION OF 2,6-TRANS-DISUBSTITUTED PIPERIDINES USING OSMIUM-CATALYZED ASYMMETRIC DIHYDROXYLATION - APPLICATION TO THE SYNTHESIS OF (+)-EPIDIHYDROPINIDINE AND (+)-SOLENOPSIN-A

被引：16

作者：

TAKAHATA, H

INOSE, K

ARAYA, N

MOMOSE, T

机构：

[1] Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Toyama, 930-01

来源：

HETEROCYCLES | 1994年 / 38卷 / 09期

关键词：

D O I：

10.3987/COM-94-6803

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An asymmetric synthesis of (+)-epidihydropinidine (1) and (+)-solenopsin A (2) has been achieved by starting with the Sharpless asymmetric dihydroxylation of the alpha-amino acid-derived N-alkenylurethanes (3) followed by subsequent aminocyclization.

引用

页码：1961 / 1964

页数：4

共 20 条

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