A NEW PROCEDURE FOR CONSTRUCTION OF 2,6-TRANS-DISUBSTITUTED PIPERIDINES USING OSMIUM-CATALYZED ASYMMETRIC DIHYDROXYLATION - APPLICATION TO THE SYNTHESIS OF (+)-EPIDIHYDROPINIDINE AND (+)-SOLENOPSIN-A

被引:16
作者
TAKAHATA, H
INOSE, K
ARAYA, N
MOMOSE, T
机构
[1] Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Toyama, 930-01
关键词
D O I
10.3987/COM-94-6803
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An asymmetric synthesis of (+)-epidihydropinidine (1) and (+)-solenopsin A (2) has been achieved by starting with the Sharpless asymmetric dihydroxylation of the alpha-amino acid-derived N-alkenylurethanes (3) followed by subsequent aminocyclization.
引用
收藏
页码:1961 / 1964
页数:4
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