CARBONYL OXIDE CHEMISTRY .2. SUBSTITUENT AND SOLVENT EFFECTS ON THE CHEMICAL BEHAVIOR OF CARBONYL-OXIDES

被引：14

作者：

IESCE, MR ^{[1
]}

CERMOLA, F ^{[1
]}

GRAZIANO, ML ^{[1
]}

SCARPATI, R ^{[1
]}

机构：

[1] UNIV NAPOLI FEDERICO II,DIPARTIMENTO CHIM ORGAN & BIOL,I-80134 NAPLES,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 01期

关键词：

D O I：

10.1039/p19940000147

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Comparison of the behaviour in polar and apolar solvents at various concentrations of the monoaryl carbonyl oxides 1 bearing an electron-withdrawing or an electron-donating group, respectively, on the aryl substituent is reported. The results are consistent with the conversion pathways reported in Scheme 1 and show that the electron-donating group increases the intramolecular oxygen-transfer potential of the system. It is also proposed that under some experimental conditions the carbonyl oxides so substituted mainly isomerize into dioxiranes 11.

引用

页码：147 / 152

页数：6

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