ADDITION OF DIMESITYLSILYLENE TO OLEFINS - A REINVESTIGATION

被引：28

作者：

ZHANG, S ^{[1
]}

WAGENSELLER, PE ^{[1
]}

CONLIN, RT ^{[1
]}

机构：

[1] N TEXAS STATE UNIV,DEPT CHEM,CTR ORGANOMET RES & EDUC,DENTON,TX 76203

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 11期

关键词：

D O I：

10.1021/ja00011a034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have reinvestigated the report that dimesitylsilylene adds nonstereospecifically to cis- and trans-2-butene. Stereospecific addition of dimesitylsilylene to cis- and trans-2-pentenes and -4-octenes produced the corresponding siliranes. A photoisomerization pathway is also reported for these siliranes. A probable explanation for the earlier and spurious interpretation is given.

引用

页码：4278 / 4281

页数：4

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