FURTHER-STUDIES ON THE PHOTOLYSIS OF FERROCENYL ETHERS IN METHANOL

被引:12
作者
BAKER, C [1 ]
HORSPOOL, WM [1 ]
机构
[1] UNIV DUNDEE,DEPT CHEM,DUNDEE DD1 4HN,SCOTLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 09期
关键词
D O I
10.1039/p19790002294
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The photolysis of several ferrocenyl ethers in methanol yields products formed from α-ferrocenyl free radicals and α-ferrocenyl carbocations. The influence of adventitious acid on the reaction has been studied and the conditions for the optimisation of the radical reaction have been established. Possible mechanisms for the reaction are discussed.
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页码:2294 / 2297
页数:4
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