MICROSTRUCTURES IN THIN POLYMERIC FILMS - PHOTOCHEMICALLY PRODUCED MOLECULAR VOIDS

被引：20

作者：

GOULD, S ^{[1
]}

GRAY, KH ^{[1
]}

LINTON, RW ^{[1
]}

MEYER, TJ ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 26期

关键词：

D O I：

10.1021/ic00052a030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ligand loss photochemistry in copolymerized films of poly-cis-[Ru(Me4bpy)2(vpy)2]2+[Os(vbpy)3]2+ (Me4bpy is 4,4',5,5'-tetramethyl-2,2'-bipyridine, vpy is 4-vinylpyridine, vbpy is 4-methyl-4'-vinyl-2,2'-bipyridine) on Pt electrodes results in loss of [-Ru(Me4bpy)2]2+ and the creation of molecular voids. The vpy binding sites in the poly[Os(vbpy)3]2+,vpy films which remained were used to coordinate [-Os(PMe2Ph)3Cl2] following reduction of mer-Os(PMe2Ph)3Cl3 at the underlying electrode. By using masking techniques, it was possible to incorporate the Os(II) complex with spatial control.

引用

页码：5521 / 5525

页数：5

共 18 条

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GOULD S, 1991, THESIS U N CAROLINA

[12]

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