GLYCIDYL METHACRYLATE AND N-VINYLPYRROLIDINONE COPOLYMERS - SYNTHESIS AND NUCLEAR-MAGNETIC-RESONANCE CHARACTERIZATION

被引：21

作者：

HUNTER, TC ^{[1
]}

PRICE, GJ ^{[1
]}

机构：

[1] UNIV BATH,SCH CHEM,CLAVERTON DOWN,BATH BA2 7AY,AVON,ENGLAND

来源：

POLYMER | 1994年 / 35卷 / 16期

关键词：

POLY(GLYCIDYL METHACRYLATE); VINYLPYRROLIDINONE COPOLYMERS; NMR CHARACTERIZATION;

D O I：

10.1016/0032-3861(94)90919-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(glycidyl methacrylate) and water-soluble copolymers of glycidyl methacrylate with N-vinylpyrrolidinone were prepared by free-radical-initiated solution polymerization in chloroform. Polymer microstructure was investigated by high-field H-1 and C-13 nuclear magnetic resonance (n.m.r.), H-1 decoupled C-13 n.m.r., H-1-C-13 correlation n.m.r. and 135 DEPT (distortionless enhancement by polarization transfer) n.m.r. The combined use of these techniques allowed unequivocal C-13 and H-1 n.m.r. assignments of carbons and protons to be established. Copolymer composition was thus determined from H-1 n.m.r.

引用

页码：3530 / 3534

页数：5

共 21 条

[1]

ARBUZOVA IA, 1959, VYSOKOMOL SOEDIN, V1, P455

[2]

CUPPLES AL, 1970, ADV CHEM SER, V92, P173

[3] GLYCIDYL METHACRYLATE TERT-BUTYL ACRYLATE COPOLYMERS - SYNTHESIS, CHARACTERIZATION, AND THERMAL STUDIES [J].

DHAL, PK ;

BABU, GN .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (08) :1817-1829

[4] MICROSTRUCTURE ELUCIDATION OF GLYCIDYL METHACRYLATE ALKYL ACRYLATE COPOLYMERS BY C-13-NMR SPECTROSCOPY [J].

DHAL, PK ;

BABU, GN ;

NANDA, RK .

MACROMOLECULES, 1984, 17 (06) :1131-1135

[5] SOL-GEL BEHAVIOR AND IMAGE-FORMATION IN POLY(GLYCIDYL METHACRYLATE) AND ITS COPOLYMERS WITH ETHYL ACRYLATE [J].

FEIT, ED ;

WURTZ, ME ;

KAMMLOTT, GW .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1978, 15 (03) :944-947

[6]

HOSONO T, 1979, CHEM PHARM BULL, V27, P58

[7]

IWAKURA Y, 1967, MAKROMOLEKUL CHEM, V104, P26

[8]

Kalal J., 1974, J POLYM SCI, V47, P155

[9]

KALAL J, 1978, J POLYM SCI POLYM S, V62, P251

[10]

KOCHNOV IM, 1964, VYSOKOMOL SOEDIN, V6, P791

← 1 2 3 →