IDENTIFICATION OF SOME ACIDS FROM AUTOXIDATION OF METHYL LINOLEATE

被引：25

作者：

HORVAT, RJ

MCFADDEN, WH

NG, H

LANE, WG

LEE, A

LUNDIN, RE

SCHERER, JR

SHEPHERD, AD

机构：

[1] Western Regional Research Laboratory, Albany, 94710, California

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1969年 / 46卷 / 02期

关键词：

D O I：

10.1007/BF02541216

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The acids from autoxidation of methyl linoleate have been analyzed as their methyl esters by combined capillary gas chromatography-mass spectrometry (GC-MS). The principal components were hexanoic, trans-2-octenoic, suberic and azelaic acid. Minor components included formic, pentanoic, heptanoic, trans-2-heptenoic, octanoic and nonanoic acid. In addition, trans-2,3-epoxy-octanoic acid was isolated as its methyl ester by preparative GLC and was identified by means of NMR, high resolution MS, IR and by conversion to a known derivative. © 1969 AOCS Press.

引用

页码：94 / &

共 12 条

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