A USEFUL PRECURSOR FOR SULFUR MONOXIDE TRANSFER

被引：22

作者：

ABUYOUSEF, IA ^{[1
]}

HARPP, DN ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL,PQ H3A 2K6,CANADA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 02期

关键词：

D O I：

10.1016/0040-4039(94)02247-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

When triphenylmethanesulfenyl chloride (8) (or its thio 9 and dithio 10 homolog) is treated with adamantylideneadamantane (11), adamantylideneadamantane thiirane (12) is produced (92%). Compound 12 was treated with m-chloroperoxybenzoic acid (m-CPBA) forming adamantylideneadamantane thiirane 1-oxide (13) in 99% isolated yield. The structures of 12 and 13 were established by H-1 and C-13 NMR, mass spectrometry as well as by X-ray analysis. Sulfoxide 13 decomposes smoothly to deliver sulfur monoxide in good yield to various dienes.

引用

页码：201 / 204

页数：4

共 24 条

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