SOLVATION OF INORGANIC COMPLEXES IN OCTANOL-WATER, HEXANOL-WATER, AND RELATED MICROEMULSIONS

被引：7

作者：

AHMED, S ^{[1
]}

BURGESS, J ^{[1
]}

CAPPER, G ^{[1
]}

FELLOWES, NC ^{[1
]}

PATEL, MS ^{[1
]}

机构：

[1] UNIV LEICESTER, DEPT CHEM, LEICESTER LE1 7RH, ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)88204-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solubilities of tris(ethylmaltolato)iron(III) have been determined in dry 1-octanol, 1-hexanol and isobutanol and in the limited ranges of alcohol-water bi nary mixtures accessible for these alcohols. The observed pattern is discussed in terms of particularly favourable synergic solvation in the mixed solvents and is compared with solvation patterns indicated by the solvatochromic iron(II) complex Fe(CN)2(bipy)2.

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页码：1145 / 1148

页数：4

相关论文

共 33 条

[1]

AITO A, 1991, TRACE ELEMENTS HLTH

[2] 2-BUTANOL-WATER SYSTEM IN THE PRESENCE OF SODIUM-CHLORIDE AND POTASSIUM-CHLORIDE [J].

APELBLAT, A ;

MANZUROLA, E .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1990, 94 (06) :653-657

[3] EVALUATION OF THE EXCESS GIBBS ENERGY OF MIXING IN BINARY ALCOHOL-WATER MIXTURES FROM THE LIQUID-LIQUID PARTITION DATA IN ELECTROLYTE-WATER-ALCOHOL SYSTEMS [J].

APELBLAT, A .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1990, 94 (10) :1128-1134

[4] CHELATION-THERAPY FOR METHYLMERCURY(II) POISONING - SYNTHESIS AND DETERMINATION OF SOLUBILITY PROPERTIES OF MEHG(II) COMPLEXES OF THIOL AND DITHIOL ANTIDOTES [J].

ARNOLD, AP ;

CANTY, AJ ;

MOORS, PW ;

DEACON, GB .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1983, 19 (04) :319-327

[5]

BEATTY E, UNPUB CAN J CHEM

[6] SOLVATION OF TRIS-MALTOLATOALUMINIUM(III) AND RELATED COMPLEXES IN METHANOL WATER MIXTURES [J].

BURGESS, J ;

PATEL, MS .

INORGANICA CHIMICA ACTA, 1990, 170 (02) :241-243

[7] SOLVATOCHROMISM AND SOLVATION OF TERNARY IRON-DIIMINE-CYANIDE COMPLEXES [J].

BURGESS, J ;

RADULOVIC, S ;

SANCHEZ, F .

TRANSITION METAL CHEMISTRY, 1987, 12 (06) :529-536

[8]

BURGESS J, UNPUB J PHARM PHARM

[9]

BURGESS J, 1992, IN PRESS T MET CHEM, V17

[10] OCTANOL WATER PARTITION-COEFFICIENTS AS A MODEL SYSTEM FOR ASSESSING ANTIDOTES FOR METHYLMERCURY(II) POISONING, AND FOR STUDYING MERCURIALS WITH MEDICINAL APPLICATIONS [J].

CANTY, AJ ;

MOORS, PW ;

DEACON, GB .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1984, 22 (01) :65-72

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