SOLVATION OF INORGANIC COMPLEXES IN OCTANOL-WATER, HEXANOL-WATER, AND RELATED MICROEMULSIONS

被引：7

作者：

AHMED, S ^{[1
]}

BURGESS, J ^{[1
]}

CAPPER, G ^{[1
]}

FELLOWES, NC ^{[1
]}

PATEL, MS ^{[1
]}

机构：

[1] UNIV LEICESTER, DEPT CHEM, LEICESTER LE1 7RH, ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)88204-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solubilities of tris(ethylmaltolato)iron(III) have been determined in dry 1-octanol, 1-hexanol and isobutanol and in the limited ranges of alcohol-water bi nary mixtures accessible for these alcohols. The observed pattern is discussed in terms of particularly favourable synergic solvation in the mixed solvents and is compared with solvation patterns indicated by the solvatochromic iron(II) complex Fe(CN)2(bipy)2.

引用

收藏

页码：1145 / 1148

页数：4

相关论文

共 33 条

[11] SOLUTION CHEMISTRY OF GALLIUM AND INDIUM 3-HYDROXY-4-PYRIDINONE COMPLEXES INVITRO AND INVIVO [J].

CLEVETTE, DJ ;

LYSTER, DM ;

NELSON, WO ;

RIHELA, T ;

WEBB, GA ;

ORVIG, C .

INORGANIC CHEMISTRY, 1990, 29 (04) :667-672

[12] WATER-DRAGGING EFFECT - A NEW EXPERIMENTAL HYDRATION PARAMETER RELATED TO HYDROGEN-BOND-DONOR ACIDITY [J].

FAN, WZ ;

ELTAVAR, N ;

TESTA, B ;

KIER, LB .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (12) :4764-4766

[13] NEUTRAL WATER-SOLUBLE POST-TRANSITION-METAL CHELATE COMPLEXES OF MEDICAL INTEREST - ALUMINUM AND GALLIUM TRIS(3-HYDROXY-4-PYRONATES) [J].

FINNEGAN, MM ;

LUTZ, TG ;

NELSON, WO ;

SMITH, A ;

ORVIG, C .

INORGANIC CHEMISTRY, 1987, 26 (13) :2171-2176

[14]

GIANDOMENICO CM, IN PRESS 6TH P INT S

[15] THE ANOMALOUS HYDROPHILIC CHARACTER OF PROLINE [J].

GIBBS, PR ;

RADZICKA, A ;

WOLFENDEN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4714-4715

[16]

Griffin WC., 1954, J SOC COSMET CHEM, V5, P249, DOI DOI 10.1002/JPS.2600581203

[17]

GRIFFIN WC, 1979, SUBSTITUTION CONSTAN, P49

[18]

HEFTER GT, 1991, J CHEM SOC FARADAY T, V87, P591, DOI 10.1039/ft9918700591

[19]

KELLAND LR, 1992, CANCER RES, V52, P822

[20] PREDICTION OF THE DISTRIBUTION CONSTANT OF SOME SOLUTES CONTAINING HYDROPHILIC FUNCTIONAL-GROUPS FROM DATA ON THE SOLUBILITY OF WATER IN ORGANIC-SOLVENTS [J].

KOJIMA, I ;

DAVIS, SS .

SEPARATION SCIENCE AND TECHNOLOGY, 1985, 20 (2-3) :131-151

← 1 2 3 4 →