DIRECT MEASUREMENT OF THE REACTION-RATE FOR CIS-]TRANS PHOTOISOMERIZATION OF STILBENE

被引:58
作者
SUMITANI, M
NAKASHIMA, N
YOSHIHARA, K
机构
[1] Institute for Molecular Science, Okazaki, 444, Myodaiji
基金
日本学术振兴会;
关键词
D O I
10.1016/0009-2614(79)87195-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rate constants are reported for cis-trans isomerization of stilbene, obtained by monitoring fluorescence generated by two consecutive picosecond light pulses. The main reaction is shown to occur in the singlet manifold via perpendicular singlet state with a lifetime shorter than a few picoseconds. © 1979.
引用
收藏
页码:255 / 257
页数:3
相关论文
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