ANALYTICAL PYROLYSIS OF HUMIC SUBSTANCES - PITFALLS, LIMITATIONS, AND POSSIBLE SOLUTIONS

被引:204
作者
SAIZJIMENEZ, C
机构
[1] Instituto de Recursos Naturales y Agrobiologia, Consejo Superior de Investigaciones Cientificas, 41080 Sevilla
关键词
D O I
10.1021/es00060a005
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Analytical pyrolysis is a technique currently used for investigating structural features of complex macromolecular materials. However, pitfalls appear td be widespread in pyrolysis studies of humic substances, and serious limitations can be experienced during the analytical procedure due to thermal reactions and configuration of the pyrolysis units-and chromatographic systems. Pyrolysis presents inconsistencies for chemical studies, and the interpretation of the chemical structure of humic substances in light of information provided by pyrolysis data is, to say the least, hazardous. This paper examines possible solutions to some of the problems encountered in pyrolysis.
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页码:1773 / 1780
页数:8
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