THE BEHAVIOR OF ESTERS IN THE PRESENCE OF TETRAMETHYLAMMONIUM SALTS AT ELEVATED-TEMPERATURES - FLASH PYROLYSIS OR FLASH CHEMOLYSIS

被引：148

作者：

DELEEUW, JW

BAAS, M

机构：

[1] Netherlands Institute for Sea Research (NIOZ), Division of Marine Biogeochemistry, 1790 AB Den Burg, Texel

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1993年 / 26卷 / 03期

关键词：

ESTERS; FLASH CHEMOLYSIS; FLASH PYROLYSIS; PYROLYSIS; TETRAMETHYLAMMONIUM SALTS;

D O I：

10.1016/0165-2370(93)80065-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Flash-heating experiments with model compounds such as tomato cutin, octadecyl octadecanoate, hexadecanol, triacontanol and L-alpha-lecithin with and without tetraalkylammonium salts, in particular tetramethylammonium hydroxide (TMAH), show that we have to discriminate between pyrolysis products sensu stricto and products resulting from bond breaking induced by chemical reagents at elevated temperatures. This discrimination is required to improve the structural elucidation of the macromolecules to be analyzed.

引用

页码：175 / 184

页数：10

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