SYNTHESIS AND MOLECULAR-STRUCTURE OF (NBU4)2(PB[PT(C6F5)4]2), THE 1ST LEAD(II) COMPOUND LINEARLY BONDED TO 2 METAL ATOMS

被引：44

作者：

USON, R

FORNIES, J

FALVELLO, LR

USON, MA

USON, I

机构：

[1] Departamento de Quimica Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, Zaragoza

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 18期

关键词：

D O I：

10.1021/ic00044a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trinuclear compound (NBu4)2{Pb[Pt(C6F5)4)2} which has been prepared in 82% yield, displays a linear Pt-Pb-Pt moiety. Eight Pb...o-F short contacts and a stereochemically inactive lone pair on the lead atom are other striking features in the anion of this unprecedented complex. The Pb-Pt distances arc 2.769 (2) and 2.793 (2) angstrom, the average Pb...o-F contact is 2.845 angstrom, and the Pt-Pb-Pt angle is 178.6 (1)-degrees.

引用

页码：3697 / 3698

页数：2