LIGHT PARAFFIN OXIDATIVE CONVERSION IN A SILENT ELECTRIC-DISCHARGE

被引：30

作者：

SHEPELEV, SS

GESSER, HD

HUNTER, NR

机构：

[1] Department of Chemistry, University of Manitoba, Winnipeg

来源：

PLASMA CHEMISTRY AND PLASMA PROCESSING | 1993年 / 13卷 / 03期

关键词：

SILENT DISCHARGE; OXIDATION OF LIGHT PARAFFINS; EXPERIMENTAL; METHANOL; ETHANOL; FORMALDEHYDE; ACETALDEHYDE;

D O I：

10.1007/BF01465877

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Methane, ethane, and their mixtures with oxygen have been passed through the silent electric discharge at various operating conditions. Besides carbon oxides and water, formaldehyde and methanol.from methane and acetaldehyde and ethanol from ethane were the other major products. The effect of temperature, pressure, discharge voltage, contact time, and oxygen concentration have been examined. The rate of oxygen consumption is almost independent of oxygen concentration and depends mainly on the discharge voltage. The selectivities of methanol formation from methane and ethanol formation from ethane were 20 and 15%, respectively.

引用

页码：479 / 488

页数：10

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