PRACTICAL APPLICATION OF POTENTIAL-PH DIAGRAMS FOR AU-CS(NH2)(2)-H2O AND AG-CS(NH2)(2)-H2O SYSTEMS FOR LEACHING GOLD AND SILVER WITH ACIDIC THIOUREA SOLUTION

被引:33
作者
GASPAR, V
MEJEROVICH, AS
MERETUKOV, MA
SCHMIEDL, J
机构
[1] TECH UNIV KOSICE,DEPT NONFERROUS MET,CS-04385 KOSICE,SLOVAKIA
[2] GINALMAZZOLOTO MOSCOW,MOSCOW 103614,RUSSIA
关键词
D O I
10.1016/0304-386X(94)90073-6
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The possibility of gold and silver extraction from products obtained during treatment of copper anodic slimes has been investigated through the construction of potential-pH diagrams for Au-CS(NH2)(2)-H2O and Ag-CS(NH2)(2)-H2O systems. The effect of leach parameters such as thiourea and ferric-ion concentrations in the solution and level of the redox potential were considered. Optimum conditions for gold extraction of 99.8% are leach time of 1 h at the concentration of thiourea 10 g/L and concentration of ferric ion as oxidant 5.0 g/L. The redox potential connected with optimum leaching conditions was 500-523 mV (versus S.H.E.).
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页码:369 / 381
页数:13
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