A NEW ISOMER OF THE CIS-[CO(CYCLEN)CL-2](+) CATION (CYCLEN=1,4,7,10-TETRAAZACYCLODODECANE)

被引:18
作者
CASTILLOBLUM, SE [1 ]
SOSATORRES, ME [1 ]
机构
[1] UNIV NACL AUTONOMA MEXICO,FAC QUIM,DIV ESTUDIOS POSGRADO,COYOACAN 04510,DF,MEXICO
关键词
D O I
10.1016/0277-5387(94)00245-A
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This work describes the preparation of a new complex, 1, and its perchlorate salt 2 when cyclen (1,4,7,10-tetraazacyclododecane) and CoCl2.6H(2)O are reacted in anhydrous methanol. H-1 and C-13 NMR spectroscopies were used to determine the absolute configuration of the new coordination compound.
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页码:223 / 229
页数:7
相关论文
共 15 条
[1]   BASE-CATALYZED AQUATION OF ALPHA-BETA-SYN-CHLORO-[1,9-BIS(2'-PYRIDYL)-2,5,8-TRIAZANONANE]-COBALT(III) AND ALPHA-BETA-ANTI-CHLORO-[1,9-BIS(2'-PYRIDYL)-2,5,8-TRIAZANONANE]-COBALT(III) AND BROMO-[1,9-BIS(2'-PYRIDYL)-2,5,8-TRIAZANONANE]-COBALT(III) AND BROMO-[1,11-BIS(2'-PYRIDYL)-2,6,10-TRIAZAUNDECANE]-COBALT(III) CATIONS - AN UNUSUALLY BASE-SENSITIVE HALOGENOPENTAMINE COBALT(III) SYSTEM5 [J].
AHMED, E ;
CHATTERJEE, C ;
COOKSEY, CJ ;
TOBE, ML ;
WILLIAMS, G ;
HUMANES, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04) :645-654
[2]   COMPLEXES OF COBALT(3) WITH A CYCLIC TETRADENTATE SECONDARY AMINE [J].
BOSNICH, B ;
POON, CK ;
TOBE, ML .
INORGANIC CHEMISTRY, 1965, 4 (08) :1102-&
[3]  
CASTILLOBLUM SE, IN PRESS
[4]   COMPLEXES OF COBALT(3) AND RHODIUM(3) WITH A CYCLIC TETRADENTATE SECONDARY AMINE [J].
COLLMAN, JP ;
SCHNEIDE.PW .
INORGANIC CHEMISTRY, 1966, 5 (08) :1380-&
[5]   MECHANISM AND STERIC COURSE OF OCTAHEDRAL AQUATION .19. AQUATION OF A LABILE TRANS ISOMER OF DICHLORO(1,4,8,11-TETRAAZACYCLOTETRADECANE)COBALT(III) CATION [J].
COOKSEY, CJ ;
TOBE, ML .
INORGANIC CHEMISTRY, 1978, 17 (06) :1558-1562
[6]   SYNTHESIS AND CRYSTAL-STRUCTURE OF 2 STEREOCHEMICAL ISOMERS OF THE TRANS-DICHLORO(1,4,8,11-TETRAAZACYCLOTETRA-DECANE)CHROMIUM(III) CATION [J].
FLORESVELEZ, LM ;
SOSARIVADENEYRA, J ;
SOSATORRES, ME ;
ROSALESHOZ, MJ ;
TOSCANO, RA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (12) :3243-3247
[8]  
ITAKA Y, 1974, INORG CHEM, V13, P2886
[9]   PROTON-EXCHANGE AND BASE-CATALYZED-HYDROLYSIS OF THE CATIONS TRANS-DICHLORO[(RSSR)-1,4,8,11-TETRA-AZACYCLOTETRADECANE]COBALT(III) AND CIS-DICHLORO[RRRR(SSSS)-1,4,8,11-TETRA-AZACYCLOTETRADECANE]-COBALT(III) [J].
LICHTIG, J ;
SOSA, ME ;
TOBE, ML .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (04) :581-585
[10]   CARBONATO(1,4,7,10-TETRAAZACYCLODODECANE)COBALT(III) PERCHLORATE MONOHYDRATE [J].
LOEHLIN, JH ;
FLEISCHER, EB .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (NOV15) :3063-3066