POLYMER ELECTROLYTES BASED ON MODIFIED POLYSACCHARIDES .2. POLYETHER-MODIFIED CELLULOSICS

被引：36

作者：

SCHOENENBERGER, C ^{[1
]}

LENEST, JF ^{[1
]}

GANDINI, A ^{[1
]}

机构：

[1] INPG,ECOLE FRANCAISE PAPETERIE & IND GRAPH,F-38402 ST MARTIN DHERES,FRANCE

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 13-14期

关键词：

POLYMER ELECTROLYTES; POLYETHER NETWORKS; POLYSACCHARIDES; CELLULOSE ETHERS; OLIGOETHER ISOCYANATES; LITHIUM PERCHLORATE; GLASS TRANSITION TEMPERATURE; VISCOELASTIC PROPERTIES; IONIC CONDUCTIVITY; FREE-VOLUME BEHAVIOR; WLF CONSTANTS;

D O I：

10.1016/0013-4686(95)00178-H

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In order to improve the film-forming properties of polyether-based polymer electrolytes a new family of materials was synthesized. The structures described in this work involve a cellulosic ether backbone on which oligoethers were grafted and crosslinked in various proportions via urethane chemistry and to which lithium perchlorate was subsequently added as a source of ionic species. The resulting networks were fully characterized in terms of glass transition temperature, dynamic mechanical properties and ionic conductivity. With respect to the optimized polyether-based networks studied previously, the introduction of polysaccharide chains does not alter the basic features neither qualitatively nor quantitatively.

引用

页码：2281 / 2284

页数：4

共 22 条

[1] TRIBLOCK COPOLYMERS AND NETWORKS INCORPORATING OLIGO (OXYETHYLENE) CHAINS [J].

ALLOIN, F ;

SANCHEZ, JY ;

ARMAND, M .

SOLID STATE IONICS, 1993, 60 (1-3) :3-9

[2]

ANDREI M, 1990, 2ND INT S POL EL, P107

[3] NEW POLYAMIDE ETHER ELECTROLYTES [J].

BENRABAH, D ;

SANCHEZ, JY ;

ARMAND, M .

ELECTROCHIMICA ACTA, 1992, 37 (09) :1737-1741

[4] A NOVEL SOLID POLYMER ELECTROLYTE - SYNTHESIS AND CHARACTERIZATION [J].

CALLENS, S ;

LENEST, JF ;

GANDINI, A ;

ARMAND, M .

POLYMER BULLETIN, 1991, 25 (04) :443-450

[5]

GOURNAY E, 1984, THESIS NATIONAL POLY

[6]

KILLIS A, 1980, MAKROMOL CHEM-RAPID, V1, P595

[7] ELECTROLYTES FOR SOLID-STATE BATTERIES - GLASS-TRANSITION TEMPERATURE OF POLYETHER NETWORKS WITH AND WITHOUT ALKALI-METAL SALTS [J].

LENEST, JF ;

GANDINI, A .

POLYMER BULLETIN, 1989, 21 (03) :347-351

[8] A NEW POLYMER NETWORK FOR IONIC-CONDUCTION [J].

LENEST, JF ;

CALLENS, S ;

GANDINI, A ;

ARMAND, M .

ELECTROCHIMICA ACTA, 1992, 37 (09) :1585-1588

[9]

LENEST JF, 1988, BRIT POLYM J, V20, P253

[10] INFLUENCE OF LICLO4 ON THE PROPERTIES OF POLYETHER NETWORKS - SPECIFIC VOLUME AND GLASS-TRANSITION TEMPERATURE [J].

LENEST, JF ;

GANDINI, A ;

CHERADAME, H ;

COHENADDAD, JP .

MACROMOLECULES, 1988, 21 (04) :1117-1120

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