5-HEXENYL CYCLIZATION

被引:52
作者
SCHMID, P
GRILLER, D
INGOLD, KU
机构
[1] Division of Chemistry, National Research Council of Canada, Ottawa, Ontario
关键词
D O I
10.1002/kin.550110309
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The cyclization of the 5‐hexenyl radical to form the cyclopentylmethyl radical has been reexamined by kinetic EPR spectroscopy at temperatures between 183 and 232°K in cyclopropane solvent. The rate constant, kc for this important radical rearrangement can be represented by (Formula Presented.) where Θ = 2.3RT kcal/mol. Copyright © 1979 John Wiley & Sons, Inc.
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页码:333 / 338
页数:6
相关论文
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