THE 1ST EXAMPLE OF TRANSITION-METAL-CATALYZED HYDROSELENATION OF ACETYLENES

被引：64

作者：

KUNIYASU, H ^{[1
]}

OGAWA, A ^{[1
]}

SATO, KI ^{[1
]}

RYU, I ^{[1
]}

SONODA, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 38期

关键词：

HYDROSELENATION; BENZENESELENOL; ACETYLENE; TRANSITION METAL CATALYST; MARKOVNIKOV ADDUCT; VINYL SELENIDE;

D O I：

10.1016/S0040-4039(00)61136-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of transition metal complexes catalyzed the regioselective hydroselenation of acetylenes. In particular, the palladium acetate-catalyzed reaction afforded the Markovnikov adducts with high selectivity.

引用

页码：5525 / 5528

页数：4