CONSTITUENTS OF ERYTHROXYLON MONOGYNUM ROXB .V. SOLVOLYSIS OF ERYTHROXYLOL B AND DIHYDROERYTHROXYLOL B TOLUENE-P-SULPHONATES

被引：13

作者：

FAIRLIE, JC

MCCRINDLE, R

MURRAY, RDH

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 16期

关键词：

D O I：

10.1039/j39690002115

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The toluene-p-sulphonates (I) and (II) of erythroxylol B and its saturated analogue have been solvolysed in buffered acetic acid. Each leads to approximately equal amounts of two bridgehead acetates, (III) and (IV) from (I), (XIII), and (XIV) from (II). The rate of solvolysis of (II) is twelve times greater than that of neopentyl tosylate at 100°.

引用

页码：2115 / +

页数：1