STUDY OF THE KINETICS OF HYDROGEN EVOLUTION REACTION ON NICKEL-ZINC POWDER ELECTRODES

被引：148

作者：

CHEN, LL

LASIA, A

机构：

[1] Departement de chimie, Université de Sherbrooke, Sherbrooke, Québec

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1992年 / 139卷 / 11期

关键词：

D O I：

10.1149/1.2069055

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrodes prepared by pressing Ni and Zn powders (50%-100% Ni) at room temperature were studied for the hydrogen evolution reaction in 1M NaOH after leaching out zinc in 30% NaOH. Although the exchange current densities of these electrodes are similar, the Tafel slopes and eta250 decrease with the decrease in the nickel content as the surface roughness increases. The mechanism and kinetics of the HER were studied using the ac impedance technique. It was found that this reaction proceeds via Volmer-Heyrovsky mechanism, and the kinetic parameters were determined.

引用

页码：3214 / 3219

页数：6

共 32 条

[21] KINETICS OF HYDROGEN EVOLUTION ON NICKEL ELECTRODES
LASIA, A
RAMI, A
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 294 (1-2): : 123 - 141
[22] Lenel F. V., 1980, POWDER METALLURGY PR
[23] Levie R, 1967, ADV ELECTROCHEMISTRY, V6, P329
[24] LOS P, IN PRESS J ELECTROAN
[25] LOS P, UNPUB J APPL ELECTRO
[26] Macdonald J.R., 1987, IMPEDANCE SPECTROSCO
[27] THE APPLICABILITY AND POWER OF COMPLEX NON-LINEAR LEAST-SQUARES FOR THE ANALYSIS OF IMPEDANCE AND ADMITTANCE DATA
MACDONALD, JR
SCHOONMAN, J
LEHNEN, AP
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 131 (JAN): : 77 - 95
[28] KINETICS OF HYDROGEN EVOLUTION ON NI-AL ALLOY ELECTRODES
RAMI, A
LASIA, A
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (04) : 376 - 382
[29] RAT IA, 1990, J APPL ELECTROCHEM, V20, P32
[30] Sluyters-Rehbach M., 1984, COMPR TREAT, V9, P177

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