ALLYLIC SULFONES AS ALLYL ANION EQUIVALENTS - HOMOALLYLIC ALCOHOLS FROM METAL-CATALYZED REACTIONS OF SULFONES WITH ALDEHYDES AND KETONES

被引：28

作者：

CLAYDEN, J ^{[1
]}

JULIA, M ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CHIM LAB,CNRS,F-75231 PARIS 05,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 16期

关键词：

D O I：

10.1039/c39940001905

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of allylic sulfones with diethylzinc, catalysed by palladium(0), gives nucleophilic organometallic species, which react in situ with carbonyl compounds to give homoallylic alcohols in high yield.

引用

页码：1905 / 1906

页数：2

共 40 条

[1] CYTOCHALASIN SUPPORT STUDIES .10. NUCLEOPHILIC AND ELECTROPHILIC MERCAPTANYLATIONS VIA 2-(TRIMETHYLSILYL)ETHANETHIOL-DERIVED REAGENTS
ANDERSON, MB
RANASINGHE, MG
PALMER, JT
FUCHS, PL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (13) : 3125 - 3127
[2] ALKYL-OXYGEN FISSION IN CARBOXYLIC ESTERS .8. ESTERS OF PARA-METHYLTHIO-DIPHENYLCARBINOLS AND PARA-METHYLSULPHONYL-DIPHENYLCARBINOLS
BALFE, MP
DABBY, RE
KENYON, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1951, (FEB): : 382 - 385
[3] BONNER WA, 1966, CHEM ORGANIC SULPHUR, V2, P35
[4] CONVENIENT DESULFONYLATION REACTIONS OF CYCLIC SULFONES WITH ULTRASONICALLY DISPERSED POTASSIUM
CHOU, T
YOU, ML
[J]. TETRAHEDRON LETTERS, 1985, 26 (37) : 4495 - 4498
[5] ULTRASONICALLY DISPERSED POTASSIUM IN ORGANIC-SYNTHESIS - REACTIONS WITH UNSATURATED CYCLIC SULFONES
CHOU, TS
YOU, ML
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (11) : 2224 - 2226
[6] ULTRASONICALLY DISPERSED POTASSIUM IN ORGANIC-SYNTHESIS - WATER-ACCELERATION IN REDUCTIVE C-S BOND-CLEAVAGE REACTIONS
CHOU, TS
HUNG, SH
PENG, ML
LEE, SJ
[J]. TETRAHEDRON LETTERS, 1991, 32 (29) : 3551 - 3554
[7] CINTAS P, 1992, SYNTHESIS-STUTTGART, P248
[8] ORTHO-SUBSTITUTED UNSYMMETRICAL BIARYLS FROM ARYL TERT-BUTYL SULFONES
CLAYDEN, J
JULIA, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (22) : 1682 - 1683
[9] Clayden J., UNPUB
[10] THE BASIC REDUCTIVE FISSION OF SULPHONES
DABBY, RE
KENYON, J
MASON, RF
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1952, (DEC): : 4881 - 4882

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