ORGANOTIN COMPLEXES WITH ETHYL AND BENZYL SULPHOXIDES

被引：30

作者：

KITCHING, W

MOORE, CJ

DODDRELL, D

机构：

[1] Department of Chemistry, University of Queensland, St. Lucia, QLD

[2] Department of Chemistry, Indiana University, Bloomington, IN

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 06期

关键词：

D O I：

10.1071/CH9691149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of complexes of methyltin halides with dibenzyl, diethyl, and methyl benzyl sulphoxides has been prepared and characterized. Vibrational and proton magnetic resonance spectra have been employed to allow suggestions as to the structures of the complexes. The change from dimethyl sulphoxide to sulphoxides with larger steric requirements and presumably dissimilar basicities is sufficient to allow the isolation of complexes of different stoicheiometries and structures. The magnetic inequivalence of the methylene groups flanking sulphur is influenced seriously by oxygen coordination to tin. © 1969, CSIRO. All rights reserved.

引用

页码：1149 / &