ANALYSIS OF THE HIGH-RESOLUTION SPECTRUM OF AMMONIA ((NH3)-N-14) IN THE NEAR-INFRARED REGION, 6400-6900-CM(-1)

被引:89
作者
LUNDSBERGNIELSEN, L
HEGELUND, F
NICOLAISEN, FM
机构
[1] AARHUS UNIV,DEPT CHEM,DK-8000 AARHUS,DENMARK
[2] UNIV COPENHAGEN,HC ORSTED INST,DEPT CHEM,DK-2100 COPENHAGEN,DENMARK
关键词
D O I
10.1006/jmsp.1993.1280
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The near-infrared absorption spectrum of 14NH3 covering the 6400-6900 cm-1 region has been obtained at a resolution of 0.005 cm-1 using a Fourier transform spectrometer. The spectrum is very complex, with many squeezed or blended lines which cannot be resolved even by Doppler-limited spectroscopy. A total of 1710 lines have been observed, and 381 rotational-vibrational transitions have been assigned to the combination band v1 + v3 and by the overtone band 2v3. © 1993 Academic Press, Inc.
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页码:230 / 245
页数:16
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