The PF2(a 4A2) radical has been generated by flowing PF3 through a dc discharge using He or Ar carrier ps. The PF2(a 4A2-X B-2(1)) low-resolution emission spectrum has been analyzed to obtain upsilon0, omega1', omega2' and some anharmonic constants. The radiative lifetime of the PF2(a 4A2) state is greater-than-or-equal-to 1.9 ms.