DOUBLE-LAYERED TETRATHIAFULVALENE AS A NOVEL ELECTRON-DONOR

被引：34

作者：

MATSUO, K ^{[1
]}

TAKIMIYA, K ^{[1
]}

ASO, Y ^{[1
]}

OTSUBO, T ^{[1
]}

OGURA, F ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIGASHIHIROSHIMA 739,JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 07期

关键词：

D O I：

10.1246/cl.1995.523

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A double-layered tetrathiafulvalenophane with four alkylenedithio spacers has been synthesized as a novel electron donor. Its structure has been elucidated by an X-ray crystal analysis to have a pair of face-to-face tetrathiafulvalenes with a small cavity in the center. Its electronic spectrum and cyclic voltammetry show a transannular interaction between both TTF units.

引用

页码：523 / 524

页数：2

共 6 条

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[5] 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE FROM CARBON-DISULFIDE AND ALKALINE METAL
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