GENERATION OF CATION RADICALS FROM ENAMINES AND THEIR REACTIONS WITH OLEFINS

被引：82

作者：

NARASAKA, K

OKAUCHI, T

TANAKA, K

MURAKAMI, M

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.2099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cation radicals of enamines, generated by the oxidation with Ce(IV) compounds, react with electron-rich olefins to give the addition products. The formal alpha-alkylation of formylacetate is realized by the reaction of 3-(1-pyrrolidinyl)propenoate and olefins by the use of tetrabutylammonium cerium(IV) nitrate as an oxidant.

引用

页码：2099 / 2102

页数：4