LAMBDA(3)-PHOSPHINOCARBENES LAMBDA(5)-PHOSPHAACETYLENES

被引：39

作者：

BERTRAND, G

REED, R

机构：

[1] Laboratoire de Chimie de Coordination, CNRS, 31077 Toulouse Cedex

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 137卷

关键词：

D O I：

10.1016/0010-8545(94)03005-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds were the first representatives of stable compounds having properties approaching those of rear carbenes. Theoretical as well as spectroscopic studies suggest a multiply bonded formulation and a singlet ground state. The dual nature of the phosphinocarbenes (carbene and phosphorus-carbon multiple bond) is demonstrated by their chemical reactivity. All presently available data concerning the title compounds are reported.

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页码：323 / 355

页数：33

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