ELECTROCHEMICAL DEPOSITION AND CHARACTERIZATION OF POLY(2,5-DIMETHOXYANILINE) - A NEW HIGHLY CONDUCTING POLYANILINE WITH ENHANCED SOLUBILITY, STABILITY AND ELECTROCHROMIC PROPERTIES

被引:31
作者
ZOTTI, G [1 ]
COMISSO, N [1 ]
DAPRANO, G [1 ]
LECLERC, M [1 ]
机构
[1] UNIV MONTREAL, DEPT CHIM, MONTREAL H3C 3J7, QUEBEC, CANADA
关键词
D O I
10.1002/adma.19920041110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Substituted polyanilines are of interest due to their increased solubility over polyaniline. However, early experiments showed that the substituted materials, while exhibiting a higher solubility (and thus workability), were also less conducting. Here, it is shown that dialkoxy substitution of aniline increases solubility of the polymer while not reducing the conductivity. The lower steric hindrance caused by teh methoxy groups in comparison with methyl groups is thought to be responsible. Copyright © 1992 Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:749 / 752
页数:4
相关论文
共 23 条
[1]   ANODIC OXIDATIONS OF AROMATIC AMINES .3. SUBSTITUTED ANILINES IN AQUEOUS MEDIA [J].
BACON, J ;
ADAMS, RN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (24) :6596-&
[2]   POLY(2-PROPYLANILINE) - AN ELECTROACTIVE POLYMER, SOLUBLE IN ORGANIC MEDIUM IN THE REDUCED STATE [J].
BIDAN, G ;
GENIES, EM ;
PENNEAU, JF .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 271 (1-2) :59-68
[3]   ELECTROSYNTHESIS AND PROPERTIES OF RING-SUBSTITUTED POLYANILINES [J].
CATTARIN, S ;
DOUBOVA, L ;
MENGOLI, G ;
ZOTTI, G .
ELECTROCHIMICA ACTA, 1988, 33 (08) :1077-1084
[4]   ON THE ADDITION OF PROTONS TO DERIVATIVES OF 4-AMINOAZOBENZENE [J].
CILENTO, G ;
MILLER, EC ;
MILLER, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (08) :1718-1722
[5]  
COPLIN KA, 1992, B AM PHYS SOC, V37, P506
[6]   OXIDATION OF 2,5-DIMETHYLANILINE IN NH4F.2.35 HF MEDIUM - CHARACTERISTICS OF THE RESULTING CONDUCTING POLYMER [J].
GENIES, EM ;
NOEL, P .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 296 (02) :473-490
[7]   ROLE OF RING TORSION ANGLE IN POLYANILINE - ELECTRONIC-STRUCTURE AND DEFECT STATES [J].
GINDER, JM ;
EPSTEIN, AJ .
PHYSICAL REVIEW B, 1990, 41 (15) :10674-10685
[8]   THE INSITU ELECTRON-SPIN-RESONANCE AND ELECTROCHEMICAL-BEHAVIOR OF POLY(ANILINE) ELECTRODE FILMS [J].
GLARUM, SH ;
MARSHALL, JH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (09) :2160-2165
[9]   ELECTROPOLYMERIZATION OF METHOXYANILINE - EXPERIMENTAL RESULTS AND FRONTIER ORBITAL INTERPRETATION [J].
LACROIX, JC ;
GARCIA, P ;
AUDIERE, JP ;
CLEMENT, R ;
KAHN, O .
SYNTHETIC METALS, 1991, 44 (02) :117-132
[10]   SYNTHESIS AND CHARACTERIZATION OF POLY(ALKYLANILINES) [J].
LECLERC, M ;
GUAY, J ;
DAO, LH .
MACROMOLECULES, 1989, 22 (02) :649-653