Trigonal distortions in octahedral complexes: The electronic structure of the hexaurea titanium(III) ion

被引:17
作者
Davis, P. H. [1 ]
Wood, J. S. [1 ]
机构
[1] Univ Southampton, Dept Chem, Southampton SO9 5NH, Hants, England
关键词
D O I
10.1016/0009-2614(69)85014-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The powder susceptibility data for Ti(urea)(6)I-3 is interpreted using a point charge model of D-3 symmetry in which there is no axial distortion. This is in contrast with previous work, but is compatible with the observed molecular geometry in the crystal.
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页码:466 / 468
页数:3
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