CHIRALITY PRESERVATION IN PYRROLINONE IRON TETRACARBONYL COMPLEXES - A ROUTE TO ENANTIOPURE 5-SUBSTITUTED PYRROLINONES

被引：23

作者：

HOPMAN, JCP ^{[1
]}

HIEMSTRA, H ^{[1
]}

SPECKAMP, WN ^{[1
]}

机构：

[1] UNIV AMSTERDAM,ORGAN CHEM LAB,1018 WS AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000617

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantiopure iron complex 4 reacts under the influence of BF3 . OEt(2) with allylsilanes and enol acetates through a cationic intermediate in which the chirality of 4 is preserved, yielding enantiopure 5-substituted 3-pyrrolin-2-ones.

引用

页码：617 / 618

页数：2

共 22 条

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[10] CHIRALITY PRESERVATION IN PYRROLINONE IRON TETRACARBONYL COMPLEXES - A ROUTE TO ENANTIOPURE 5-SUBSTITUTED PYRROLINONES [J].

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JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) :617-618

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