SYNTHESES, STRUCTURES, AND SOME REACTIONS OF DI-MU-HYDROXO DINUCLEAR COMPLEXES OF TUNGSTEN(IV) AND MOLYBDENUM(IV)

被引：16

作者：

REN, JG

TOMITA, H

MINATO, M

OSAKADA, K

ITO, T

机构：

[1] YOKOHAMA NATL UNIV, FAC ENGN, DEPT CHEM MAT, HODOGAYA KU, YOKOHAMA, KANAGAWA 240, JAPAN

[2] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 03期

关键词：

D O I：

10.1246/cl.1994.637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel dinuclear complexes [Cp(2)M(mu -OH)(2)MCp(2)](2+)(0Ts(-))(2) (M = Mo and W) were prepared by the reaction of Cp(2)MH(2) with Cp(2)M(OTs)(2) in aqueous acetone. Their structures were characterized by spectroscopic methods as well as by X-ray crystallography. The structure comprises a planar four membered ring consisting of alternating M and O atoms.

引用

收藏

页码：637 / 640

页数：4

相关论文

共 12 条

[1]

CAMONA E, 1987, ORGANOMETALLICS, V6, P1757

[2]

Dean, 1985, LANGES HDB CHEM, P3

[3] DI-PI-CYCLOPENTADIENYL HYDRIDES OF TANTALUM, MOLYBDENUM, AND TUNGSTEN [J].

GREEN, ML ;

PRATT, L ;

WILKINSON, G ;

MCCLEVERTY, JA .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (NOV) :4854-&

[4] THE 1ST ISOLATION AND SOME REACTIONS OF THE CATIONIC TRIHYDRIDES, [W(N-C5H5)2H3]++SO-, [MO(N-C5H5)2H3]+ISO [J].

IGARASHI, T ;

ITO, T .

CHEMISTRY LETTERS, 1985, (11) :1699-1702

[5] BIS(ETA(5)-METHYLCYCLOPENTADIENYL)DIHYDRIDOMOLYBDENUM(IV) - SYNTHESIS AND REACTIONS WITH NUCLEOPHILES IN THE PRESENCE OF PROTONIC ACIDS [J].

ITO, T ;

YODEN, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (08) :2365-2370

[6] A CONVENIENT, ONE-STEP SYNTHESIS OF THE CATIONIC ETA-3-ALLYL-MOLYBDENUM COMPLEX [(ETA-5-C5H5)2MO(ETA-3-C3H5)]+[PARA-CH3C6H4SO3]- [J].

ITO, T ;

IGARASHI, T ;

SUZUKI, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 320 (02) :C16-C18

[7] SYNTHESES AND REACTIONS OF CATIONIC CYCLIC (GAMMA-HYDROXYPROPYL)MOLYBDENUM(IV) DERIVATIVES - NEW PATHWAY FOR MOLYBDENAOXACYCLOPENTANES [J].

ITO, T ;

HAJI, K ;

SUZUKI, F ;

IGARASHI, T .

ORGANOMETALLICS, 1993, 12 (06) :2325-2331

[8] PREPARATION, CHARACTERIZATION, AND X-RAY STRUCTURE STUDIES OF TERTIARY PHOSPHINE COORDINATED MOLYBDENOCENE [J].

ITO, T ;

TOKUNAGA, T ;

MINATO, M ;

NAKAMURA, T .

CHEMISTRY LETTERS, 1991, (11) :1893-1896

[9] SELECTIVE REDUCTION OF CARBONYL GROUPS WITH SYSTEMS COMPOSED OF (ETA-5-C5H5)2MOH2 AND PROTONIC ACIDS - NEW HIGHLY REGIOSELECTIVE AND DIASTEREOSELECTIVE REDUCTION OF KETONES [J].

ITO, T ;

KOGA, M ;

KURISHIMA, S ;

NATORI, M ;

SEKIZUKA, N ;

YOSHIOKA, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (14) :988-989

[10] A NOVEL DIOXYGENASE TYPE OXYGEN INSERTION - CH BOND OXIDATION OF ISOPROPYL GROUPS IN A DIMANGANESE COMPLEX WITH MOLECULAR-OXYGEN [J].

KITAJIMA, N ;

OSAWA, M ;

TANAKA, M ;

MOROOKA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8952-8953