SYNTHESES, STRUCTURES, AND SOME REACTIONS OF DI-MU-HYDROXO DINUCLEAR COMPLEXES OF TUNGSTEN(IV) AND MOLYBDENUM(IV)

被引：16

作者：

REN, JG

TOMITA, H

MINATO, M

OSAKADA, K

ITO, T

机构：

[1] YOKOHAMA NATL UNIV, FAC ENGN, DEPT CHEM MAT, HODOGAYA KU, YOKOHAMA, KANAGAWA 240, JAPAN

[2] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 03期

关键词：

D O I：

10.1246/cl.1994.637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel dinuclear complexes [Cp(2)M(mu -OH)(2)MCp(2)](2+)(0Ts(-))(2) (M = Mo and W) were prepared by the reaction of Cp(2)MH(2) with Cp(2)M(OTs)(2) in aqueous acetone. Their structures were characterized by spectroscopic methods as well as by X-ray crystallography. The structure comprises a planar four membered ring consisting of alternating M and O atoms.

引用

页码：637 / 640

页数：4