SYNTHESIS, STRUCTURE AND PROPERTIES OF A LINEAR COPPER(I) COORDINATION POLYMER WITH TETRAKIS(ETHYLTHIO)TETRATHIAFULVALENE

被引：17

作者：

GAN, XM ^{[1
]}

MUNAKATA, M ^{[1
]}

KURODASOWA, T ^{[1
]}

MAEKAWA, M ^{[1
]}

YAMAMOTO, M ^{[1
]}

机构：

[1] KINKI UNIV,FAC SCI & TECHNOL,DEPT CHEM,OSAKA 577,JAPAN

来源：

POLYHEDRON | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1016/0277-5387(94)00426-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new linear coordination polymer composed of copper(I) cations and tetrakis(ethylthio)tetrathiafulvalene (TTC2-TTF) molecules has been synthesized by the reaction of copper(I) perchlorate and TTC2-TTF in acetone under argon. The compound, [Cu(TTC2-TTF)]ClO4, was characterized by spectroscopic and X-ray crystallographic methods. It is a 1:1 metal-ligand complex in which each of the copper(I) ions is tetrahedrally coordinated by four sulphur atoms from the bridging TTC2-TTF molecules to form coordination polymeric chains which are separated from each other by the perchlorate anions in the crystal. The complex was doped with iodine to afford {[Cu(TTC2-TTF)] ClO4}I, which exhibits a conductivity of 6 x 10(-4) S cm(-1) at 25 degrees C for a compacted pellet.

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页码：1647 / 1651

页数：5

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