SYNTHESIS OF PHEROMONES BY STEREOSELECTIVE CARBONYL OLEFINATION - UNITIZED CONSTRUCTION PRINCIPLE

被引：43

作者：

BESTMANN, HJ

VOSTROWSKY, O

机构：

[1] Institute of Organic Chemistry, University of Erlangen-Nürnberg

来源：

CHEMISTRY AND PHYSICS OF LIPIDS | 1979年 / 24卷 / 04期

关键词：

D O I：

10.1016/0009-3084(79)90118-X

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A route of synthesis for the preparation of unsaturated pheromones is presented. It permits the synthesis of monounsaturated and diunsaturated compounds, with varying position and configuration of double bonds, by stereoselective carbonyl olefination. The choice of appropriate ω-functional aldehydes and phosphoranes makes possible the synthesis of (Z)-alkenols and alkenyl acetates with the double bond in any position desired. Bifunctional synthones are used in stereoselective Wittig reactions for the preparation of diunsaturated sex attractants. © 1979.

引用

页码：335 / 389

页数：55

共 304 条

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