REACTIONS OF CYCLOHEXADIENYL CATIONS . AROMATIC ACETOXYLATION ACCOMPANYING HALOGENATION

被引：22

作者：

MYHRE, PC

OWEN, GS

JAMES, LL

机构：

[1] Department of Chemistry, Harvey Mudd College, Claremont

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 08期

关键词：

D O I：

10.1021/ja01010a033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Halogenation of 1,3,5-tri-t-butylbenzene and other alkylbenzenes with positive halogenating agents in acetic acid solvent results in the formation of aryl acetate products. Yields of aryl acetates increase upon addition of sodium acetate to the solvent. Data derived from studies of product distributions, kinetic isotope effects, and structural effects indicate that acetoxylation accompanying halogenation occurs by addition-elimination. © 1968, American Chemical Society. All rights reserved.

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页码：2115 / &

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