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[31]
Smith L., 1932, J AM CHEM SOC, V54, P1603, DOI [10.1021/ja01343a056, DOI 10.1021/JA01343A056]
REACTIONS OF CYCLOHEXADIENYL CATIONS . AROMATIC ACETOXYLATION ACCOMPANYING HALOGENATION
被引：22
作者：
MYHRE, PC
OWEN, GS
JAMES, LL
机构：
[1] Department of Chemistry, Harvey Mudd College, Claremont
关键词：
D O I：
10.1021/ja01010a033
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Halogenation of 1,3,5-tri-t-butylbenzene and other alkylbenzenes with positive halogenating agents in acetic acid solvent results in the formation of aryl acetate products. Yields of aryl acetates increase upon addition of sodium acetate to the solvent. Data derived from studies of product distributions, kinetic isotope effects, and structural effects indicate that acetoxylation accompanying halogenation occurs by addition-elimination. © 1968, American Chemical Society. All rights reserved.
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页码：2115 / &
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