COEXISTENCE OF MOBILE AND LOCALIZED-ELECTRONS IN BIS(ETHYLENE)DITHIOTETRATHIAFULVALENE (BEDT-TTF) RADICAL SALTS WITH PARAMAGNETIC POLYOXOMETALATES - SYNTHESIS AND PHYSICAL-PROPERTIES OF (BEDT-TTF)(8)[COW12O40]CENTER-DOT-5.5H2O

被引：121

作者：

GOMEZGARCIA, CJ

OUAHAB, L

GIMENEZSAIZ, C

TRIKI, S

CORONADO, E

DELHAES, P

机构：

[1] UNIV RENNES 1,CHIM SOLIDE & INORGAN MOLEC LAB,CNRS,URA 1495,F-35042 RENNES,FRANCE

[2] UNIV VALENCIA,DEPT QUIM INORGAN,E-46100 BURJASSOT,SPAIN

[3] UNIV BORDEAUX 1,CTR RECH PAUL PASCAL,CNRS,F-33600 PESSAC,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199402231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alternating layers of radicals of the π‐electron donor 1 and of polyoxonions [CoW12O40]6− (2, polyhedral representation) are contained in the title compound. Thus, organic charge carriers and inorganic electron‐acceptor components lie next to each other. Since the polyoxometalates can accommodate different metal ions at specific sites, such anions are attractive precursors for the preparation of radical cation salts with new electrical and magnetic properties. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：223 / 226

页数：4

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