STRUCTURE AND VALENCE OF THE CE/PT(111) SYSTEM

被引:58
作者
TANG, J
LAWRENCE, JM
HEMMINGER, JC
机构
[1] UNIV CALIF IRVINE,DEPT PHYS,IRVINE,CA 92717
[2] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717
来源
PHYSICAL REVIEW B | 1993年 / 48卷 / 20期
关键词
D O I
10.1103/PhysRevB.48.15342
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have studied the growth of thin cerium films on Pt(111) with x-ray photoemission spectroscopy (XPS) and low-energy electron diffraction. No ordered structures were observed for the Ce films immediately after room-temperature deposition. After heat treatment to 770 K, ordered Ce-Pt compounds were formed. For films with initial coverages greater than 3.5 ML, a hexagonal pattern with periodicity nearly twice that of Pt(111) appeared after annealing. For this 1.96X1.96 structure, the periodicity is close to that of the compound CePt2, the XPS data show a stoichiometry of CePt2.23, and the observed Ce valence is 3.07. For films having initial coverages from 0.9 to 1.8 ML, a 1.94X1.94 pattern with small satellites around the main spots appeared; the Ce valence is 3.11 and the stoichiometry is CePt3. Between 2.1 and 3.2 ML, a 1.96X1.96 pattern with a superimposed 1.96X1.96 net rotated by 30 degrees was observed with valence around 3.09. Studies of the take-off angle dependence of the emission indicate that the valence has the same value near the surface as in the bulk. We have also performed CO and O-2 adsorption studies and found extremely low sticking coefficients for these molecules on the 1.96X1.96 CePt2.23 surface. Since these well-characterized single-crystal Ce compound films are highly suitable for photoemission experiments and adsorption studies, we have attempted to formulate empirical rules for predicting which compound species will be generated by similar means.
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页码:15342 / 15352
页数:11
相关论文
共 27 条
[1]   ADSORPTION AND COMPOUND FORMATION OF YBONNI(100) [J].
ANDERSEN, JN ;
ONSGAARD, J ;
NILSSON, A ;
ERIKSSON, B ;
MARTENSSON, N .
SURFACE SCIENCE, 1988, 202 (1-2) :183-203
[2]  
[Anonymous], 1993, ELEMENTS XRAY DIFFRA
[3]   GROWTH OF EU ON PD(111) STUDIED BY X-RAY AND UV PHOTOEMISSION AND CRYSTALLOGRAPHIC PROPERTIES AS DETERMINED BY REFLECTION-HIGH-ENERGY-ELECTRON-DIFFRACTION AND X-RAY-DIFFRACTION STUDIES [J].
BERTRAN, F ;
GOURIEUX, T ;
KRILL, G ;
RAVETKRILL, MF ;
ALNOT, M ;
EHRHARDT, JJ ;
FELSCH, W .
PHYSICAL REVIEW B, 1992, 46 (12) :7829-7840
[4]   PHOTOEMISSION-STUDY OF FORMATION AND OXIDATION OF A CERIUM-COPPER INTERFACE [J].
BRAATEN, NA ;
GREPSTAD, JK ;
RAAEN, S .
PHYSICAL REVIEW B, 1989, 40 (11) :7969-7972
[5]  
CAMPAGNA M, 1987, HDB PHYSICS CHEM RAR, V10, pCH63
[6]   ELECTRONIC-STRUCTURE OF CE AND ITS INTERMETALLIC COMPOUNDS [J].
FUGGLE, JC ;
HILLEBRECHT, FU ;
ZOLNIEREK, Z ;
LASSER, R ;
FREIBURG, C ;
GUNNARSSON, O ;
SCHONHAMMER, K .
PHYSICAL REVIEW B, 1983, 27 (12) :7330-7341
[7]   GAMMA-ALPHA-PHASE TRANSITION OF MONOLAYER CE ON W(110) [J].
GU, C ;
WU, X ;
OLSON, CG ;
LYNCH, DW .
PHYSICAL REVIEW LETTERS, 1991, 67 (12) :1622-1625
[8]   CONSTITUTION OF SOME REPT3 ALLOYS [J].
HARRIS, IR .
JOURNAL OF THE LESS-COMMON METALS, 1968, 14 (04) :459-&
[9]   AN EMPIRICAL ELECTRON SPECTROMETER TRANSMISSION FUNCTION FOR APPLICATIONS IN QUANTITATIVE XPS [J].
HEMMINGER, CS ;
LAND, TA ;
CHRISTIE, A ;
HEMMINGER, JC .
SURFACE AND INTERFACE ANALYSIS, 1990, 15 (05) :323-327
[10]  
HEMMINGER CS, COMMUNICATION