FLUORINE-19 NUCLEAR MAGNETIC RESONANCE IN CEF3

被引:27
作者
LEE, K
机构
[1] Varian Associates, Palo Alto, California 94303, U.S.A. Present address : IBM Research Laboratory, San Jose
关键词
D O I
10.1016/0038-1098(69)90748-0
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Nuclear magnetic resonance studies of 19F in paramagnetic CeF3 show the ionic diffusion observed earlier in LaF3 and confirm the D43d (P3cl) crystal structure proposed by X-ray measurements. Between 245° K and 500°K, the ionic diffusion is due to the relatively rapid motion of fluorine ions in g sites, with EA = 0.13 eV, D0 = 1.7 × 10-9 cm2/sec and τc = 16μsec. © 1969.
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页码:367 / &
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