THE SHAPE OF LINEAR AND STAR POLYMERS WITH AND WITHOUT EXCLUDED VOLUME

被引：37

作者：

BISHOP, M

CLARKE, JHR

REY, A

FREIRE, JJ

机构：

[1] MANHATTAN COLL,DEPT MATH COMP SCI,RIVERDALE,NY 10471

[2] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM FIS,E-28040 MADRID,SPAIN

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 05期

关键词：

D O I：

10.1063/1.460677

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The shape of isolated linear and star polymers, with and without excluded volume, has been determined by Monte Carlo simulations using a pivot algorithm. Stars with 3, 4, 5, and 6 arms are studied. The high efficiency of the pivot algorithm has allowed us to obtain accurate data for long chains. Good agreement is found with existing analytical expressions for nonexcluded volume chains and with other computer simulations for excluded volume chains.

引用

收藏

页码：4009 / 4011

页数：3

相关论文

共 48 条

[11] THE SHAPE OF TWO-DIMENSIONAL POLYMERS [J].

BISHOP, M ;

MICHELS, JPJ .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (09) :4791-4792

[12] INVESTIGATIONS OF STATIC PROPERTIES OF TWO-DIMENSIONAL BULK POLYMER SYSTEMS [J].

BISHOP, M ;

CEPERLEY, D ;

FRISCH, HL ;

KALOS, MH .

JOURNAL OF CHEMICAL PHYSICS, 1981, 75 (11) :5538-5542

[13]

BRUNS W, 1986, COLLOID POLYM SCI, V254, P325

[14] COMPUTER-SIMULATION OF DYNAMICS OF A SINGLE POLYMER-CHAIN [J].

CEPERLEY, D ;

KALOS, MH ;

LEBOWITZ, JL .

PHYSICAL REVIEW LETTERS, 1978, 41 (05) :313-316

[15] UNIVERSAL SHAPE RATIOS FOR OPEN AND CLOSED RANDOM-WALKS - EXACT RESULTS FOR ALL D [J].

DIEHL, HW ;

EISENRIEGLER, E .

JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1989, 22 (03) :L87-L91

[16] SHAPE DISTRIBUTIONS FOR GAUSSIAN MOLECULES [J].

EICHINGER, BE .

MACROMOLECULES, 1985, 18 (02) :211-216

[17] MONTE-CARLO CALCULATIONS FOR LINEAR AND STAR POLYMERS WITH INTRAMOLECULAR INTERACTIONS .1. DIMENSIONS [J].

FREIRE, JJ ;

PLA, J ;

REY, A ;

PRATS, R .

MACROMOLECULES, 1986, 19 (02) :452-457

[18] MEAN RECIPROCAL DISTANCES OF SHORT POLYMETHYLENE CHAINS - CALCULATION OF TRANSLATIONAL DIFFUSION-COEFFICIENT OF N-ALKANES [J].

FREIRE, JJ ;

HORTA, A .

JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (10) :4049-4054

[19] THE SHAPES OF OPEN AND CLOSED RANDOM-WALKS - A 1/D EXPANSION [J].

GASPARI, G ;

RUDNICK, J ;

BELDJENNA, A .

JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1987, 20 (11) :3393-3414

[20] STATISTICAL-MECHANICS OF RANDOM-FLIGHT CHAINS .5. EXCLUDED VOLUME EXPANSION AND SECOND VIRIAL-COEFFICIENT FOR LINEAR-CHAINS OF VARYING SHAPE [J].

GOBUSH, W ;

SOLC, K ;

STOCKMAYER, WH .

JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (01) :12-21

← 1 2 3 4 5 →