SURFACE-COMPOSITION OF POLY(STYRENE-D8-STYRENE) RANDOM COPOLYMERS STUDIED BY STATIC SECONDARY-ION MASS-SPECTROSCOPY

被引：27

作者：

AFFROSSMAN, S

HARTSHORNE, M

JEROME, R

MUNRO, H

PETHRICK, RA

PETITJEAN, S

VILAR, MR

机构：

[1] UNIV LIEGE,CTR EDUC & RES MACROMOLEC,B-4000 LIEGE,BELGIUM

[2] COURTAULDS PLC,COVENTRY CV6 5RS,ENGLAND

[3] CNRS,SPECTROCHIM INFRAROUGE & RAMAN LAB,F-94320 THIAIS,FRANCE

来源：

MACROMOLECULES | 1993年 / 26卷 / 20期

关键词：

D O I：

10.1021/ma00072a017

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The surface compositions of a series of random copolymers of styrene and deuteriostyrene have been determined by SIMS. The mechanism of fragmentation during the SIMS process is examined, and the contribution from naturally occurring isotopes is evaluated. The data are shown to fit a model of a completely random copolymer system if they are corrected for the effects of impurities introduced in the syntheses and for the contribution from C-13.

引用

页码：5400 / 5404

页数：5

共 10 条

[1] AFFROSSMAN S, 1992, POLYMER - SOLID INTERFACES, P337
[2] ANALYSIS OF POLYMER SURFACES BY SIMS .2. FINGERPRINT SPECTRA FROM SIMPLE POLYMER-FILMS
BRIGGS, D
[J]. SURFACE AND INTERFACE ANALYSIS, 1982, 4 (04) : 151 - 155
[3] STATIC SECONDARY ION MASS-SPECTROMETRY AND X-RAY PHOTOELECTRON-SPECTROSCOPY OF DEUTERIUM-SUBSTITUTED AND METHYL-SUBSTITUTED POLYSTYRENE
CHILKOTI, A
CASTNER, DG
RATNER, BD
[J]. APPLIED SPECTROSCOPY, 1991, 45 (02) : 209 - 217
[4] SURFACE-INDUCED ORIENTATION OF SYMMETRIC, DIBLOCK COPOLYMERS - A SECONDARY ION MASS-SPECTROMETRY STUDY
COULON, G
RUSSELL, TP
DELINE, VR
GREEN, PF
[J]. MACROMOLECULES, 1989, 22 (06) : 2581 - 2589
[5] DOREGO B, IN PRESS
[6] SURFACE ENRICHMENT IN AN ISOTOPIC POLYMER BLEND
JONES, RAL
KRAMER, EJ
RAFAILOVICH, MH
SOKOLOV, J
SCHWARZ, SA
[J]. PHYSICAL REVIEW LETTERS, 1989, 62 (03) : 280 - 283
[7] SURFACE AND TRACE ANALYSIS BY HIGH-RESOLUTION TIME-OF-FLIGHT SECONDARY ION MASS-SPECTROMETRY
NIEHUIS, E
HELLER, T
JURGENS, U
BENNINGHOVEN, A
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1989, 7 (03): : 1823 - 1828
[8] FILMS OF MIXTURES OF DEUTERATED AND HYDROGENATED POLYMERS - AN HREELS STUDY
VILAR, MR
SCHOTT, M
PIREAUX, JJ
GREGOIRE, C
CAUDANO, R
LAPP, A
DASILVA, JL
DOREGO, AMB
[J]. SURFACE SCIENCE, 1989, 211 (1-3) : 782 - 789
[9] INVESTIGATION OF DIFFUSION IN POLYSTYRENE USING SECONDARY ION MASS-SPECTROSCOPY
WHITLOW, SJ
WOOL, RP
[J]. MACROMOLECULES, 1989, 22 (06) : 2648 - 2652
[10] DETERMINATION OF THE CONCENTRATION PROFILE AT THE SURFACE OF D-PS H-PS BLENDS USING HIGH-RESOLUTION ION-SCATTERING TECHNIQUES
ZHAO, X
ZHAO, W
SOKOLOV, J
RAFAILOVICH, MH
SCHWARZ, SA
WILKENS, BJ
JONES, RAL
KRAMER, EJ
[J]. MACROMOLECULES, 1991, 24 (22) : 5991 - 5996

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