SYNTHESES VIA ANODICALLY PRODUCED PHENOXENIUM IONS - APPLICATIONS IN THE FIELD OF PEPTIDES AND CARBOHYDRATES

被引：51

作者：

RIEKER, A

BEISSWENGER, R

REGIER, K

机构：

[1] Institut für Organische Chemie der Universität

来源：

TETRAHEDRON | 1991年 / 47卷 / 4-5期

关键词：

D O I：

10.1016/S0040-4020(01)87054-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sterically hindered phenols are anodically oxidized to the corresponding phenoxenium ions which react with O- and N-nucleophiles to give cyclohexadienyl-protected nucleophiles. 4-Acyloxy substituted phenoxenium ions can transfer the acyl group to nucleophiles. A synthesis of dipeptides and glycoamino acids based on this principle is developed.

引用

页码：645 / 654

页数：10