ASYMMETRIC AMINATION OF CARBOXYLIC-ACIDS VIA A DIELS-ALDER STRATEGY

被引：53

作者：

GOUVERNEUR, V ^{[1
]}

GHOSEZ, L ^{[1
]}

机构：

[1] UNIV CATHOLIQUE LOUVAIN,CHIMIE ORGAN SYNTHESE LAB,PL LOUIS PASTEUR 1,B-1348 LOUVAIN,BELGIUM

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 39期

关键词：

AMINO ACIDS; NITROSO COMPOUNDS; AZADIENES; CYCLOADDITION; AMINATION;

D O I：

10.1016/S0040-4039(00)92382-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-azadienes 1 which are readily prepared from acyl chlorides react with high facial selectivity with the chiral carbamoyl nitroso dicnophile 2. Reduction and hydrolysis of the adducts yield enantiomerically pure amino acids.

引用

页码：5349 / 5352

页数：4

共 22 条

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