PALLADIUM-CATALYZED POLYCYCLIZATION OF DIENYNES TO GIVE CARBOCYCLIC ANGULARLY BISANELLATED CYCLOHEXADIENE DERIVATIVES

被引：45

作者：

MEYER, FE

BRANDENBURG, J

PARSONS, PJ

DEMEIJERE, A

机构：

[1] UNIV GOTTINGEN,INST ORGAN CHEM,TAMMANNSTR 2,W-3400 GOTTINGEN,GERMANY

[2] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 05期

关键词：

D O I：

10.1039/c39920000390

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various 2-bromododeca-1,11-dien-6-ynes 1a,b, 8 and trans- or cis-10a,b when subjected to Heck reaction conditions, cleanly undergo palladium-catalysed biscyclizations followed by an electrocyclic rearrangement to form tricyclic cyclohexadienes 5a,b, 9 and cis- or trans-11a,b as sole products (7 examples).

引用

页码：390 / 392

页数：3

共 21 条

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