A NEW INORGANIC METALLOCYCLE CONTAINING TIN, SULFUR, PHOSPHORUS AND NITROGEN - CRYSTAL AND MOLECULAR-STRUCTURE OF SPIROBICYCLIC ME2SN(SPPH2NPPH2S)2

被引：66

作者：

HAIDUC, I ^{[1
]}

SILVESTRU, C ^{[1
]}

ROESKY, HW ^{[1
]}

SCHMIDT, HG ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

POLYHEDRON | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)87055-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new inorganic heterocycle is obtained by reacting potassium tetraphenyldithio-imidodiphosphinate with trimethyltin and dimethyltin chlorides, in benzene. X-ray diffraction analysis reveals a spirocyclic structure with the dimethyltin moiety as the coordination centre with non-planar six-membered SnS2P2N rings. The coordination at tin is nearly perfectly octahedral, with equal Sn-S [273.3(2) and 273.7(2) pm] and P-S bonds [200.9(3) and 201.9(3) pm]. The S-Sn-S and H3C-Sn-CH3 units are co-linear.

引用

页码：69 / 75

页数：7

共 61 条

[1] STEREOELECTRONIC PROPERTIES OF METALLOENZYMES .4. BIS(IMIDOTETRAPHENYLDITHIODIPHOSPHINO-S,S')COPPER(II) AS A TETRAHEDRAL MODEL FOR TYPE-1 COPPER(II)
BEREMAN, RD
WANG, FT
NAJDZIONEK, J
BRAITSCH, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (23) : 7266 - 7268
[2] A TRUE SQUARE-PLANAR TE(II) COMPLEX WITH BIDENTATE LIGANDS - THE PREPARATION AND CRYSTAL-STRUCTURE OF BIS(IMIDOTETRAPHENYLDITHIODIPHOSPHINO-S,S')TELLURIUM(II)
BJORNEVAG, S
HUSEBYE, S
MAARTMANNMOE, K
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (03): : 195 - 202
[3] THE STRUCTURE OF THE TETRAPHENYLDITHIOIMIDODIPHOSPHINATE ION
CEAOLIVARES, R
NOTH, H
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1987, 42 (12): : 1507 - 1509
[4] DIMETHYLGOLD(III) COMPLEXES - SYNTHESIS OF SEVERAL COMPOUNDS WITH AUC2S2 COORDINATION - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(CH3)2AUSC2H5]2
CHEN, HW
PAPARIZOS, C
FACKLER, JP
[J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 96 (02): : 137 - 149
[5] TRANSITION-METAL COMPLEXES OF INORGANIC SULFUR NITROGEN LIGANDS
CHIVERS, T
EDELMANN, F
[J]. POLYHEDRON, 1986, 5 (11) : 1661 - 1699
[6] PREPARATION AND CRYSTAL STRUCTURE OF A STERICALLY UNENCUMBERED TETRAHEDRAL CHELATE COMPLEX CONTAINING A NIS4 CORE, [SPME2NPME2S]2NI2
CHURCHILL, MR
COOKE, J
WORMALD, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (23) : 6518 - +
[7] CRYSTAL STRUCTURE OF BIS(IMIDOTETRAMETHYLDITHIODIPHOSPHINO-S,S)NICKEL(II), A TETRAHEDRAL COMPLEX WITH AN NIS4 CORE
CHURCHILL, MR
COOKE, J
FENNESSEY, JP
WORMALD, J
[J]. INORGANIC CHEMISTRY, 1971, 10 (05) : 1031 - +
[8] CRYSTAL STRUCTURE OF BIS(IMIDOTETRAMETHYLDITHIODIPHOSPHINO-S,S)IRON(II), A COMPLEX WITH A TETRAHEDRAL FES4 CORE
CHURCHILL, MR
WORMALD, J
[J]. INORGANIC CHEMISTRY, 1971, 10 (08) : 1778 - +
[9] CZERNUSZEWICZ E, 1980, INORG CHIM ACTA, V40, P199
[10] STEREOCHEMISTRY OF 4 COORDINATE BIS(IMIDODIPHOSPHINATO)METAL(II)CHELATE COMPLEXES
DAVISON, A
SWITKES, ES
[J]. INORGANIC CHEMISTRY, 1971, 10 (04) : 837 - &

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