A NEW INORGANIC METALLOCYCLE CONTAINING TIN, SULFUR, PHOSPHORUS AND NITROGEN - CRYSTAL AND MOLECULAR-STRUCTURE OF SPIROBICYCLIC ME2SN(SPPH2NPPH2S)2

被引：66

作者：

HAIDUC, I ^{[1
]}

SILVESTRU, C ^{[1
]}

ROESKY, HW ^{[1
]}

SCHMIDT, HG ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

POLYHEDRON | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)87055-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new inorganic heterocycle is obtained by reacting potassium tetraphenyldithio-imidodiphosphinate with trimethyltin and dimethyltin chlorides, in benzene. X-ray diffraction analysis reveals a spirocyclic structure with the dimethyltin moiety as the coordination centre with non-planar six-membered SnS2P2N rings. The coordination at tin is nearly perfectly octahedral, with equal Sn-S [273.3(2) and 273.7(2) pm] and P-S bonds [200.9(3) and 201.9(3) pm]. The S-Sn-S and H3C-Sn-CH3 units are co-linear.

引用

页码：69 / 75

页数：7

共 61 条

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