SOLVENT DEPENDENT ESTER ELIMINATION-REACTIONS IN THE PREPARATION OF MIXED-METAL OXO CLUSTERS - THE SYNTHESIS OF PBSN2(MU(3)-O)(OBU(T))(4)(OAC)(4)

被引：18

作者：

CARUSO, J

HAMPDENSMITH, MJ

DUESLER, EN

机构：

[1] UNIV NEW MEXICO,DEPT CHEM,ALBUQUERQUE,NM 87131

[2] UNIV NEW MEXICO,CTR MICROENGINEERED CERAM,ALBUQUERQUE,NM 87131

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 10期

关键词：

D O I：

10.1039/c39950001041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between Sn(OBu(t))(4) and Pb(OAc)(4) has been studied as a function of the nature of the reaction solvent: in refluxing toluene, ester elimination results in the quantitative formation of PbSn2(mu(3)-O)(OBu(t))(4)(OAC)(4) which has been characterized in solution by H-1, Sn-119 and Pb-207 NMR and in the solid state by single-crystal X-ray diffraction, whereas in pyridine, reaction of the same two species results in ligand exchange forming Sn(OBu(t))(3)(OAc) . pyridine and Pb(OAc)(3)(OBu(t)).

引用

页码：1041 / 1042

页数：2

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